Molecular motions in poly(ethylene-
co-norbornene) were studied in a temperature range well below its glass transition point by a few techniques based on the NMR phenomenon. Temperature dependencies of proton
spin-lattice relaxation times
T1 (at 200 MHz and at 30.2 MHz), proton spin-lattice relaxation time in the
rotating frame T1ρ (at 68 kHz) and frequency dispersion of proton spin-lattice off-resonance relaxation times in the rotating frame were determined for the
copolymer. Analysis of
1H NMR relaxation data permitted characterization of local motions occurring in the copolymer i.e. rotation of
methyl groups around C
3 axes, reorientations of
methylene groups and motions of segments of
polymer chains including
norbornene groups.