Publikacje

Langmuir, 2017, 33 (36), 8856–8868
M. Dobies, M. Makrocka-Rydzyk, J. Jenczyk, M. Jarek, R. J. Spontak, S. Jurga

Molecular Dynamics Study of Polystyrene-b-poly(ethylene oxide) Asymmetric Diblock Copolymer Systems

Two polystyrene-b-poly(ethylene oxide) (PS-b-PEO) diblock copolymers differing in molecular mass (49 and 78 kDa) but possessing the same PEO cylindrical morphology are examined to elucidate their molecular dynamics. Of particular interest here is the molecular motion of the PEO blocks involved in the rigid amorphous fraction (RAF). An analysis of complementary thermal calorimetry and X-ray scattering data confirms the presence of microphase-separated morphology as well as semicrystalline structure in each copolymer. Molecular motion within the copolymer systems is monitored by dielectric and nuclear magnetic resonance spectroscopies. The results reported herein reveal the existence of two local Arrhenius-type processes attributed to the noncooperative local motion of PEO segments involved in fully amorphous and rigid amorphous PEO microphases. In both systems, two structural relaxations governed by glass-transition phenomena are identified and assigned to cooperative segmental motion in the fully amorphous phase (the α process) and the RAF (the αc process). We measure the temperature dependence of the dynamics associated with all of the processes mentioned above and propose that these local processes are associated with corresponding cooperative segmental motion in both copolymer systems. In marked contrast to the thermal activation of the α process as discerned in both copolymers, the αc process appears to be a sensitive probe of the copolymer nanostructure. That is, the copolymer with shorter PEO blocks exhibits more highly restricted cooperative dynamics of PEO segments in the RAF, which can be explained in terms of the greater constraint imposed by the glassy PS matrix on the PEO blocks comprising smaller cylindrical microdomains.
Wszystkie Publikacje
  • Ogłoszenia

      Wszystkie ogłoszenia
  • Seminaria

    • dr Guillaume Brunetti, JEOL (EUROPE) SAS

      Latest developments and applications of Cryo Transmission Electron Microscopy
      Sala Wykładowa - 26.10.2017 16:00

    • dr inż. Mirosław Werwiński, IFM PAN

      Sala Wykładowa - 02.11.2017 16:00

    Seminaria

Kontakt | Baza kontaktów | RSS | Login
© 2017 CENTRUM NANOBIOMEDYCZNE UAM | ul. Umultowska 85, PL61614 Poznań, Poland | tel.+48 61 829 67 04.

Developed by drupalninja.pl